Firefox starts with standard welcome tab and one pinned tab (Twitter)
Which tab has focus (i.e., which actually loads on startup) Welcome or Twitter?
Test with Welcome having focus (if not already).
Test with only Welcome (i.e., do not leave Twitter open).
Test with opening to a blank page (about:blank) rather then Welcome (or Twitter).
If none of that makes any difference, test with a new clean Profile.
In times past, maybe even today, not sure, when particular files (names escape me) became huge, they would affect start up times (or reloading into memory, as the case may be).
FF (now) uses tons of files, & one is not apt to know what they do, if they're needed..., & while what may seem "big", may or may not be. (Like various .sqlite files, start out large, by default. And then things that may be withing your /storage/ directory, like who knows what that is, can be huge & maybe that... ? Mine is 40 MB - total, which I believe to be rather small in the scheme of things.)
Fire 750, bring back 250.
Mozilla/5.0 (Windows; U; Windows NT 6.1; en-US; rv:1.9.1.19) Gecko/20110420 SeaMonkey/2.0.14 Pinball CopyURL+ FetchTextURL FlashGot NoScript